Strengthening of carbon nanotube fiber using ecofriendly triblock copolymer and newly designed characterization via low-frequency noise

Abstract

In this study, carbon nanotube fibers (CNTFs) were strengthened by densifying and reorienting CNT bundles using a triblock copolymer (poly (propylene glycol)–block-poly (ethylene glycol)–block-poly (propylene glycol (PPG–PEG–PPG)). This copolymer possesses a unique combination of hydrophilic and hydrophobic molecules, enabling it to easily penetrate and expand the distance between bundles. Through a stretching process after impregnation, the CNTFs induced a structural alignment of the bundles, resulting in high integration of the CNT bundles. The microstructural analysis of the fiber cross-section revealed an increased number of aligned CNTs along the fiber direction, concomitant with a reduction in the bundle-to-bundle distance owing to bundle aggregation. The highly aligned structure showed an average specific tensile strength of 0.536 N/tex and specific elastic modulus of 66.3 N/tex, which is an increase of 175 % and 252 %, respectively, compared to the pristine CNTF. The polymer infiltration stretching method effectively aggregated CNT bundles and removed macro voids within the CNTF. Additionally, the densification and alignment of CNTFs were characterized through novel low-frequency noise measurement and analysis. Understanding the nanoscale structure and morphology of CNTFs in nanoscale will provide valuable guidance for building enhanced strengthening strategies. © 2024 Elsevier Ltd