Oak (Quercus robur) Acorn Peel as a Low-Cost Adsorbent for Hexavalent Chromium Removal from Aquatic Ecosystems and Industrial Effluents

Abstract

The efficiency of low-cost, abundantly available local forestry waste, oak (Quercus robur) acorn peel (OP), to remove toxic Cr(VI) from aqueous solutions was studied in a batch system as a function of contact time, adsorbate concentration, adsorbent dosage, and pH. In an equilibrium time of 420 min, the maximum Cr removal by OP at pH 2 and 10 was 100 and 97 %, respectively. The sorption data fitted well with Langmuir adsorption model. Evaluation using Langmuir expression presented a monolayer sorption capacity of 47.39 mg g(-1) with an equilibrium sorbent dose of 5 g L-1 and pH 7. Uptake of Cr by OP was described by pseudo-second-order chemisorption model. ICP-OES, LC-ICPMS analysis of the aqueous and solid phases revealed that the mechanism of Cr(VI) removal is by 'integrated adsorption and reduction' mechanism. ESEM-EDX and XRD analysis of OP before and after adsorption also confirmed that both adsorption and reduction of Cr(VI) to less toxic Cr3+ forms followed by complexation onto the adsorbent surface contributed to the removal of Cr(VI). Consistent with batch studies, OP effectively removed (>95 %) Cr from the real water samples collected from lake and sea. The results of this study illustrate that OP could be an economical, green, and effective biomaterial for Cr(VI) removal from natural aquatic ecosystems and industrial effluents.