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H-D exchange of pyrrolic NH protons prompted by fluoride in aprotic DMSO-d6H-D exchange of pyrrolic NH protons prompted by fluoride in aprotic DMSO-d6
- Other Titles
- H-D exchange of pyrrolic NH protons prompted by fluoride in aprotic DMSO-d6
- Authors
- 김성국
- Issue Date
- Dec-2024
- Publisher
- 한국자기공명학회
- Keywords
- Fluoride; deuterium exchange; anion receptor; calix[4]pyrrole; aprotic solvent
- Citation
- Journal of the Korean Magnetic Resonance Society, v.28, no.4, pp 38 - 43
- Pages
- 6
- Indexed
- ESCI
KCI
- Journal Title
- Journal of the Korean Magnetic Resonance Society
- Volume
- 28
- Number
- 4
- Start Page
- 38
- End Page
- 43
- ISSN
- 1226-6531
- Abstract
- The binding feature of bipyrrole-strapped calix[4]pyrrole 1 for the fluoride anion was examined by a combination of 1H and 19F NMR spectroscopy in DMSO-d6 . Receptor 1 was found to bind the fluoride anion with high affinity via two step-process. Fluoride binding to receptor 1 was proved to facilitate deuterium exchange of the pyrrolic protons in the nominally aprotic deuterated solvent of DMSO-d6.
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