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Cited 18 time in webofscience Cited 20 time in scopus
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Small asymmetric anthracene-thiophene compounds as organic thin-film transistors

Authors
Shaik, BajiPark, Ji HeeAn, Tae KyuNoh, Young RiYoon, Soon ByungPark, Chan EonYoon, Young JinKim, Yun-HiLee, Sang-Gyeong
Issue Date
Sep-2013
Publisher
Pergamon Press Ltd.
Keywords
Organic thin-film transistors; Sonogashira coupling; Asymmetric anthracene derivatives; Solution processing; P-type charge carrier mobility
Citation
Tetrahedron, v.69, no.38, pp 8191 - 8198
Pages
8
Indexed
SCI
SCIE
SCOPUS
Journal Title
Tetrahedron
Volume
69
Number
38
Start Page
8191
End Page
8198
URI
https://scholarworks.gnu.ac.kr/handle/sw.gnu/73810
DOI
10.1016/j.tet.2013.07.041
ISSN
0040-4020
1464-5416
Abstract
Anthracene and thiophene compounds are promising materials for OTFTs. We report here, the synthesis, as well as the physical, thermal, and optoelectronic properties of alkyl-substituted asymmetric anthracene-thiophene compounds connected by a bridged triple bond. The target molecules were synthesized using 2-bromoanthracene as the starting material, and the proceeding reactions included alkylation, bromination, and the Sonogashira coupling reaction. The synthesized compounds were both thermally and electrochemically stable. Among the synthesized compounds, HTEA (7a) and DTEA (7b) showed mobility and on/off ratio values of 1.3x10(-1) cm(2)/V s, 2.6 x 10(6) and 2.0x10(-2) cm(2)/V s, 1.0x10(6), respectively. (C) 2013 Elsevier Ltd. All rights reserved.
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