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Electrochemical Properties of Sn/C Nanoparticles Fabricated by Pulse Wire Evaporation for Lithium Secondary Batteries

Authors
Ju, Jin-HoonPark, Sang-HuiPark, Sang-HeeLee, Han-GyeolChoi, Hyon-KwangCho, Gyu-Bong
Issue Date
Nov-2020
Publisher
American Scientific Publishers
Keywords
Anode; Sn/C; Polyamide-Imide; Pressing
Citation
Journal of Nanoscience and Nanotechnology, v.20, no.11, pp 7045 - 7050
Pages
6
Indexed
SCIE
Journal Title
Journal of Nanoscience and Nanotechnology
Volume
20
Number
11
Start Page
7045
End Page
7050
URI
https://scholarworks.gnu.ac.kr/handle/sw.gnu/72003
DOI
10.1166/jnn.2020.18832
ISSN
1533-4880
1533-4899
Abstract
In this work, bare Sn and carbon-coated Sn nanoparticles were prepared by a pulsed wire evaporation process. The effect of binder and pressing ratio on electrochemical properties of Sn/C composite electrodes was investigated to enhance the structural stability of Sn anode. The electrode containing the polyamide-imide (PAI) binder with high tensile strength (52 MPa) exhibited higher coulombic efficiency and better cycle performance compared to the electrode with the conventional polyvinylidene fluoride (PVdF) binder. The 5%-pressed Sn/C electrode with the proper porosity in the electrode demonstrated the best cycle performance corresponding to 45% of capacity retention ratio until 100 cycles.
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