Enhancing the thermoelectric performance of a Ti2FeNiSb2 double half-Heusler alloy through excess Ni-induced full-Heusler nanoprecipitates
- Authors
- Hasan, Rahidul; Gu, Yan; Kim, Se Yun; Chun, Dong Won; Lee, Kyu Hyoung
- Issue Date
- Sep-2023
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- INORGANIC CHEMISTRY FRONTIERS, v.10, no.19, pp 5662 - 5667
- Pages
- 6
- Indexed
- SCIE
SCOPUS
- Journal Title
- INORGANIC CHEMISTRY FRONTIERS
- Volume
- 10
- Number
- 19
- Start Page
- 5662
- End Page
- 5667
- URI
- https://scholarworks.gnu.ac.kr/handle/sw.gnu/68747
- DOI
- 10.1039/d3qi01132a
- ISSN
- 2052-1553
2052-1553
- Abstract
- Double half-Heuslers (DHHs) have emerged as promising candidates for thermoelectric power generation at mid-high temperatures due to their exceptional chemical and mechanical stability, as well as high electronic transport properties. However, their limited thermoelectric conversion efficiency (ZT) has hindered their practical application. In the present study, we propose an approach to enhance the ZT of DHHs by generating full-Heusler (FH) nanoprecipitates through a simple and scalable compositional tuning method. We investigate the effectiveness of this approach using Ti2FeNiSb2 as a model system. Our results reveal that FH nanoprecipitates can substantially intensify the phonon scattering in Ti2FeNiSb2, leading to an ultra-low lattice thermal conductivity of similar to 0.9 W m(-1) K-1 at 973 K. Additionally, filtering of low-energy carriers, in the presence of FH nanoprecipitates, further improves the electronic transport properties. As a result, we achieved a relatively high zT of 0.31 in Ti2FeNi1.05Sb2, which is 1.5-fold enhancement compared to the pristine Ti2FeNiSb2. These findings offer attractive opportunities for designing and developing high-performance DHH-based thermoelectric materials.
- Files in This Item
- There are no files associated with this item.
- Appears in
Collections - 공학계열 > Dept.of Materials Engineering and Convergence Technology > Journal Articles
![qrcode](https://api.qrserver.com/v1/create-qr-code/?size=55x55&data=https://scholarworks.gnu.ac.kr/handle/sw.gnu/68747)
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.