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A squaramide cage capable of binding and extracting H2PO4- and HP2O73- in highly polar protic media
- Authors
- Yang, Ju Ho; Kim, Sung Kuk
- Issue Date
- Aug-2023
- Publisher
- Royal Society of Chemistry
- Citation
- Chemical Communications, v.59, no.66, pp 9988 - 9991
- Pages
- 4
- Indexed
- SCIE
SCOPUS
- Journal Title
- Chemical Communications
- Volume
- 59
- Number
- 66
- Start Page
- 9988
- End Page
- 9991
- ISSN
- 1359-7345
1364-548X
- Abstract
- A novel squaramide cage (2) binds H2PO4- and HP2O73- with high selectivity and affinity in a highly polar protic solvent system. Receptor 2 is also able to extract these hydrophilic anions into a chloroform phase from water. The X-ray crystal structure demonstrated that compound 2 forms a complex with H2PO4- with 1 : 1 stoichiometry in the solid state.
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