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Exciplex emissive supramolecular polymer formed by tuning molecular conformation
- Authors
- Heo, Sojeong; Kim, Ka Young; Choi, Heekyoung; Kang, Seok Gyu; Choi, Wonjin; Lee, Shim Sung; Jung, Sung Ho; Jung, Jong Hwa
- Issue Date
- 28-Aug-2020
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- NANOSCALE, v.12, no.32, pp.16685 - 16689
- Indexed
- SCIE
SCOPUS
- Journal Title
- NANOSCALE
- Volume
- 12
- Number
- 32
- Start Page
- 16685
- End Page
- 16689
- ISSN
- 2040-3364
- Abstract
- We demonstrated the exciplex emission of supramolecular polymers (Bipy-1) possessing bipyridine and pyrene moieties. The distinctive exciplex emission of the supramolecular polymers was controlled by tuning the molecular conformation in different composition ratios of a mixed DMSO/H2O solution. The strong exciplex emission of the supramolecular polymer I with yellow emission was a consequence of the intramolecular charge-transfer interactions in a mixed DMSO/H2O (60 : 40-1 : 99 v/v) solution.
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