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Electrochemical conversion of biomass-derived aldehydes into fine chemicals and hydrogen: A review
- Authors
- Theerthagiri, Jayaraman; Karuppasamy, K.; Park, Juhyeon; Rahamathulla, Nihila; Kumari, M. L. Aruna; Souza, Marcielli K. R.; Cardoso, Eduardo S. F.; Murthy, Arun Prasad; Maia, Gilberto; Kim, Hyun-Seok; Choi, Myong Yong
- Issue Date
- Jun-2023
- Publisher
- Springer Verlag
- Keywords
- Biomass-derived aldehydes; Furfural; 5-Hydroxymethylfurfural; Electrochemical oxidization; Hydrogenation; Hybrid water electrolyzer; Value-added chemicals; Hydrogen fuel
- Citation
- Environmental Chemistry Letters, v.21, no.3, pp 1555 - 1583
- Pages
- 29
- Indexed
- SCIE
SCOPUS
- Journal Title
- Environmental Chemistry Letters
- Volume
- 21
- Number
- 3
- Start Page
- 1555
- End Page
- 1583
- ISSN
- 1610-3653
1610-3661
- Abstract
- The decrease in fossil fuel usage and the projected 28% increase in the global energy demand by 2040 are calling for advanced methods to convert modern biomass into fine chemicals. For instance, biomass-derived aldehydes appear as promising substitutes for the chemical and fuel industries. Here, we review electrochemical upgrading of furfural and 5-hydroxymethylfurfural with a focus on catalysis and selectivity mechanisms. We also present hybrid water electrolysis systems for production of hydrogen and chemicals. We discuss electrochemical oxidation or hydrogenation of furfural and 5-hydroxymethylfurfural using metal oxides, noble metals, transition metal nanoparticles and alloys, and nonoxides. We compare electrochemical processes with combustion, chemical, thermochemical, and biochemical processes for biomass conversion.
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