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Improved stereoselectivity in intramolecular S(N)2 ' cyclization through use of mechanistic principles
- Authors
- Seo, Woo Duck; Curtis-Long, Marcus J.; Jeong, Seong Hun; Jun, Tae Hong; Yang, Min Suk; Park, Ki Hun
- Issue Date
- 17-Jan-2007
- Publisher
- GEORG THIEME VERLAG KG
- Keywords
- oxazolidin-2-one; intramolecular cyclization; stereoselectivity; A(1,3) strain; alpha-hydroxy-beta-amino acids
- Citation
- SYNTHESIS-STUTTGART, no.2, pp 209 - 214
- Pages
- 6
- Indexed
- SCIE
SCOPUS
- Journal Title
- SYNTHESIS-STUTTGART
- Number
- 2
- Start Page
- 209
- End Page
- 214
- ISSN
- 0039-7881
1437-210X
- Abstract
- Valine and alanine were converted into the corresponding alpha-hydroxy-beta-amino acids through intramolecular S(N)2' cyclization. The novel cyclization protocol relied upon the use of N-benzyl-protected carbarnates derived from a-amino acids
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