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Solvent-Dependent Networking of O2S2-Macrocycle with Silver Perchlorate into One- and Two-Dimensional Coordination Polymers
- Issue Date
- Mar-2010
- Publisher
- AMER CHEMICAL SOC
- Citation
- CRYSTAL GROWTH & DESIGN, v.10, no.3, pp 1033 - 1036
- Pages
- 4
- Indexed
- SCI
SCIE
SCOPUS
- Journal Title
- CRYSTAL GROWTH & DESIGN
- Volume
- 10
- Number
- 3
- Start Page
- 1033
- End Page
- 1036
- ISSN
- 1528-7483
1528-7505
- Abstract
- The solvent-dependent double-stranded one-dimensional (1-D) coordination polymer [Ag2L2(ClO4)(2)](n) (1) and another 1-D polymer {[Ag2L2(CH3CN)]center dot 2ClO(4)}(n) (2a) with the shape of a cut of tube along the long axis were obtained in the reactions of a 16-membered O2S2-macrocycle L with silver(1) perchlorate in DCM/MeOH and CH3CN, respectively. Time-dependent crystallization experiments unambiguously show that 2a is a kinetic product and transforms into a thermodynamically more stable [AgLClO4](n) (2b) with a two-dimensional square-grid structure.
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