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A Chromo-Fluorogenic Tetrazole-Based CoBr2 Coordination Polymer Gel as a Highly Sensitive and Selective Chemosensor for Volatile Gases Containing Chloride
- Authors
- Lee, Hyejin; Jung, Sung Ho; Han, Won Seok; Moon, Jong Hun; Kang, Sunwoo; Lee, Jin Yong; Jung, Jong Hwa; Shinkai, Seiji
- Issue Date
- Mar-2011
- Publisher
- WILEY-V C H VERLAG GMBH
- Keywords
- chlorine; chromophores; gels; sensors; tetrazole
- Citation
- CHEMISTRY-A EUROPEAN JOURNAL, v.17, no.10, pp 2823 - 2827
- Pages
- 5
- Indexed
- SCI
SCIE
SCOPUS
- Journal Title
- CHEMISTRY-A EUROPEAN JOURNAL
- Volume
- 17
- Number
- 10
- Start Page
- 2823
- End Page
- 2827
- ISSN
- 0947-6539
1521-3765
- Abstract
- Catching chloride: A tetrazole-based ligand without long alkyl chains is used to form a coordination polymer gel with CoBr2 (1). Gel 1 has a spherical structure with a 20-30 nm diameter. More interestingly, gel 1 selectively recognizes toxic gases, such as HCl, SOCl2, (COCl)(2), and COCl2 that contain chloride atoms.
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