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A Benzodithiophene-based Semiconducting Polymer for Organic Thin Film Transistor

Authors
Hong, Jung-AKim, RanYun, Hui-JunPark, Joung-ManShin, Sung ChulKim, Yun-Hi
Issue Date
Apr-2013
Publisher
대한화학회
Keywords
Organic semiconductor; Organic thin film transistors (OTFTs); Benzodithiophene
Citation
Bulletin of the Korean Chemical Society, v.34, no.4, pp 1170 - 1174
Pages
5
Indexed
SCI
SCIE
SCOPUS
KCI
Journal Title
Bulletin of the Korean Chemical Society
Volume
34
Number
4
Start Page
1170
End Page
1174
URI
https://scholarworks.gnu.ac.kr/handle/sw.gnu/20705
DOI
10.5012/bkcs.2013.34.4.1170
ISSN
0253-2964
1229-5949
Abstract
Benzodithiophene based organic semiconducting polymer was designed and synthesized by stille coupling reaction. The structure of polymer was confirmed by NMR and IR. The weight average molecular weight (M-w) of polymer was 8,400 using GPC with polydispersity index of 1.4. The thermal, optical and electrochemical properties of polymer were characterized by TGA and DSC, UV-vis absorption and cyclic voltammetry. OTFT device using PBDT-10 exhibited the mobility of 7.2 x 10(-5) cm(2) V-1 s(-1) and I-on/I-off of 2.41 x 10(3). The film morphology and crystallinity of PBDT-10, was studied using AFM and XRD.
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