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Cited 86 time in webofscience Cited 86 time in scopus
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Alkyl Chain Length Dependence of the Field-Effect Mobility in Novel Anthracene Derivatives

Authors
Back, Jang YeolAn, Tae KyuCheon, Ye RimCha, HyojungJang, JaeyoungKim, YebyeolBaek, YonghwaChung, Dae SungKwon, Soon-KiPark, Chan EonKim, Yun-Hi
Issue Date
Jan-2015
Publisher
American Chemical Society
Keywords
organic field-effect transistor (OFET); alkyl chain length; asymmetric anthracene; structure-mobility relationship; crystal orientation
Citation
ACS Applied Materials & Interfaces, v.7, no.1, pp 351 - 358
Pages
8
Indexed
SCI
SCIE
SCOPUS
Journal Title
ACS Applied Materials & Interfaces
Volume
7
Number
1
Start Page
351
End Page
358
URI
https://scholarworks.gnu.ac.kr/handle/sw.gnu/17458
DOI
10.1021/am5063103
ISSN
1944-8244
1944-8252
Abstract
We report six asymmetric alkylated anthracene-based molecules with different alkyl side chain lengths for use in organic field-effect transistors (OFETs). Alkyl side chains can potentially improve the solubility and processability of anthracene derivatives. The crystallinity and charge mobility of the anthracene derivatives may be improved by optimizing the side chain length. The highest field-effect mobility of the devices prepared here was 0.55 cm2/(V s), for 2-(p-pentylphenylethynyl)anthracene (PPEA). The moderate side chain length appeared to be optimal for promoting self-organization among asymmetric anthracene derivatives in OFETs, and was certainly better than the short or long alkyl side chain lengths, as confirmed by X-ray diffraction measurements. © 2014 American Chemical Society.
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