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Metallosupramolecular polymers formed with silver(I) ions in aqueous solution

Authors
Li, ChenxingOk, MiraeChoi, HeekyoungJung, Jong Hwa
Issue Date
Feb-2022
Publisher
Royal Society of Chemistry
Citation
New Journal of Chemistry, v.46, no.8, pp 3551 - 3554
Pages
4
Indexed
SCIE
SCOPUS
Journal Title
New Journal of Chemistry
Volume
46
Number
8
Start Page
3551
End Page
3554
URI
https://scholarworks.gnu.ac.kr/handle/sw.gnu/1601
DOI
10.1039/d1nj05146f
ISSN
1144-0546
1369-9261
Abstract
We report supramolecular polymers of a terpyridine-based ligand with an alanine moiety (L) at three different concentrations of AgNO3 (0, 0.5, and 1.0 equiv.) in a mixture of H2O and dimethyl sulfoxide (DMSO) (1 : 1 v/v). The self-assembled L obtained without AgNO3 shows a positive circular dichroism (CD) signal indicating right-handed (P-helicity) helicity. In contrast, the self-assembled L formed in the presence of 0.5 and 1.0 equiv. of AgNO3 shows a negative CD signal indicating left-handed (M-helicity) helicity.
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자연과학대학 (화학과)
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