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Calix [4]-bis-monothiacrown-5 as a versatile building block for homo- and heterometallic coordination polymers
- Authors
- Park, In-Hyeok; Kim, Ja-Yeon; Lee, Eunji; Ju, Huiyeong; Kim, Seulgi; Lee, Joon-Hwa; Lee, Shim Sung
- Issue Date
- Aug-2016
- Publisher
- ELSEVIER SCIENCE BV
- Keywords
- Calixarene; Mercury; Potassium; Exocoordination; Coordination polymer
- Citation
- INORGANIC CHEMISTRY COMMUNICATIONS, v.70, pp 205 - 209
- Pages
- 5
- Indexed
- SCI
SCIE
SCOPUS
- Journal Title
- INORGANIC CHEMISTRY COMMUNICATIONS
- Volume
- 70
- Start Page
- 205
- End Page
- 209
- ISSN
- 1387-7003
1879-0259
- Abstract
- Exocoordination-based homonuclear and heteronuclear coordination polymers of calix [4]-bis-monothiacrown-5 (L) are reported. L reacts with HgCl2 and affords a one-dimensional (1D) coordination polymer [L(mu-Hg2Cl4)](n) (1) linked by neutral square-type Hg2Cl4 clusters. A straightforward one-pot reaction of L with a mixture of HgCl2 and KCl resulted in the isolation of a heteronuclear species [(K2L)(mu-Hg3Cl8)](n) (2) adopting a 1D polymeric structure in which the endocyclic dipotassium(I) complex cation units of L are linked by anionic open double-square type (mu-Hg3Cl8)(2-) clusters. Both products form a pseudo 3D framework via interchain H-bonds and their topological analyses were also carried out. (C) 2016 Elsevier B.V. All rights reserved.
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