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Cited 2 time in webofscience Cited 2 time in scopus
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Stainless steel promoted the electrochemical oxidation of amines into imines

Authors
Lee, KeunyoungChoi, HyebinAn, JaunKwon, Ki-Young
Issue Date
Jul-2022
Publisher
대한화학회
Keywords
amine oxidation; electrochemistry; imines; stainless steel
Citation
Bulletin of the Korean Chemical Society, v.43, no.7, pp 937 - 940
Pages
4
Indexed
SCIE
SCOPUS
KCI
Journal Title
Bulletin of the Korean Chemical Society
Volume
43
Number
7
Start Page
937
End Page
940
URI
https://scholarworks.gnu.ac.kr/handle/sw.gnu/1134
DOI
10.1002/bkcs.12542
ISSN
0253-2964
1229-5949
Abstract
We report the electrochemical oxidation of benzylamine (BA) into the imine by applying a bare stainless steel mesh (SSM) as an anode. Scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX) elemental mapping analysis confirmed that there was no corrosion on the surface of SSM after an anodic electrolysis. Based on the gas chromatography (GC) analysis and electrochemical results, it was confirmed that conversion of BA with SSM was approximately 3.3 times higher than with Pt electrode. This work suggests that the anodic electrolysis with a bare SSM could be a promising route to electrochemical oxidation of BA in the absence of oxidizing agents.
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