Enhanced thermal conductivity and sinterability of magnesia via nano-powder addition: Control of pore formation and densification
  • Kim, Dong-Myeong
  • Jang, Hye-Jeong
  • Moon, Young Kook
  • Choi, Jong‑Jin
  • Hahn, Byung‑Dong
  • ... Cha, Hyun-Ae
  • 외 2명
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초록

MgO ceramics are promising candidates for high thermal conductivity applications in next-generation electronics. However, their practical application is hindered by the extremely high sintering temperature and hygroscopic instability of MgO. In this study, dense MgO ceramics were achieved through the combined use of multi-scale micro/nano MgO powders and TiO2/Nb2O5 additives under spark plasma sintering (SPS). Notably, 5 wt% nano-MgO combined with additives enabled densification at 1200 °C with conductivities above 41 W/m·K, demonstrating the feasibility of low-temperature processing. Finally, SPS of the optimized composition achieved nearly full density and 60 W/m·K, underscoring the synergistic effect of multi-scale mixing, additives, and applied pressure, and advancing next‑gen MgO thermal‑management materials due to improved grain-boundary connectivity and heat transport. This work provides new insights into practical route for cost-effective fabrication of high-conductivity MgO ceramics at low temperature.

키워드

MagnesiaNano-powderSpark-plasma sinteringThermal conductivityThermal-management materialsSINTERING CRYSTALLINE SOLIDSBEHAVIORSIZEDIFFUSIONCERAMICSMGO
제목
Enhanced thermal conductivity and sinterability of magnesia via nano-powder addition: Control of pore formation and densification
저자
Kim, Dong-MyeongJang, Hye-JeongMoon, Young KookChoi, Jong‑JinHahn, Byung‑DongAhn, Cheol‑WooLee, Jung WooCha, Hyun-Ae
DOI
10.1016/j.jeurceramsoc.2026.118144
발행일
2026-07
유형
Article
저널명
Journal of the European Ceramic Society
46
7