Synthesis of Thienopyrrolodione-Based Copolymers and Their Application in Organic Thin-Film Transistors

  • Lee, Ji Eun; 
  • Kim, Yebyeol; 
  • Ha, Jong-Jin; 
  • An, Tae Kyu; 
  • Kim, Yun-Hi
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초록

Two thienopyrrolodione (TPD)-based polymers, 24DTT-TPD and 24DTS-TPD, were synthesized bycarrying out Stille coupling reactions. The obtained polymers were characterized by H-1 NMR, FT-IR, mass analysis, UV-visible spectroscopy, cyclic voltammetry, differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA). The deposited films were characterized by X-ray diffraction. Synthesized polymers showed good solubility in common solvents. The solution-processed organic field-effect transistors showed field-effect mobility values of 4.5x10(-5) cm(2)/Vs for 24DTT-TPD and 2.9x10(-2) cm(2)/Vs for 24DTS-TPD at optimal conditions.

키워드

Organic Transistors; Polymeric Semiconductor; Thienopyrrolodione; FIELD-EFFECT TRANSISTORS; HETEROJUNCTION SOLAR-CELLS; HIGH-PERFORMANCE; CONJUGATED POLYMERS; MOLECULAR DESIGN; DPP COPOLYMER; MOBILITY; DONOR; SEMICONDUCTORS; SELENOPHENE
제목
Synthesis of Thienopyrrolodione-Based Copolymers and Their Application in Organic Thin-Film Transistors
저자
Lee, Ji Eun; Kim, Yebyeol; Ha, Jong-Jin; An, Tae Kyu; Kim, Yun-Hi
DOI
10.1166/jnn.2017.14118
발행일
2017-08
유형
Article
저널명
Journal of Nanoscience and Nanotechnology
권
17
호
8
페이지
5662 ~ 5668