Development of novel inorganic Mn<SUP>5+</SUP>-doped BiCa<sub>2</sub>VO<sub>6</sub> vivid green pigments: its crystal structure and color properties
Development of novel inorganic Mn5+-doped BiCa2VO6 vivid green pigments: its crystal structure and color properties
  • Park, Young Ji
  • Kang, Tae Wook
  • Lee, Younki
  • Bae, Byungseo
  • Kim, Sun Woog
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초록

Novel vivid green inorganic pigments BiCa2VO6 (0 <= x <= 0.2) were synthesized through a conventional solid-state reaction method. The properties of pigments were investigated by X-ray diffraction (XRD), scanning electronic microscopy (SEM), UV-visible absorbance spectra, and X-ray photoelectron spectroscopy (XPS). The BiCa2(V1-xMnx)O-6 (0 <= x <= 0.2) pigments prepared in this study exhibited orthorhombic structure with space group Ccm21 as main phase. The Mn5+ doped BiCa2VO6 pigments showed strong optical absorption in the yellow-red light regions due to the Mn5+ d-d transitions, which is the origin of the green color. Among these pigments, the BiCa2V0.97Mn0.03O6 showed the most vivid green color and the L*, a*, and b* values are 58.79, - 23.88, and 12.18, respectively.

키워드

ColorPowders: solid-state reactionPHOTOLUMINESCENCE PROPERTYINTENSE TURQUOISEOXIDESMN5+SPECTROSCOPYCHROMOPHOREENVIRONMENTVANADATEIONS
제목
Development of novel inorganic Mn<SUP>5+</SUP>-doped BiCa<sub>2</sub>VO<sub>6</sub> vivid green pigments: its crystal structure and color properties
제목 (타언어)
Development of novel inorganic Mn5+-doped BiCa2VO6 vivid green pigments: its crystal structure and color properties
저자
Park, Young JiKang, Tae WookLee, YounkiBae, ByungseoKim, Sun Woog
DOI
10.1007/s43207-024-00428-3
발행일
2024-11
유형
Article
저널명
한국세라믹학회지
61
6
페이지
1181 ~ 1186