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Construction of the Azacyclic Core of Tabernaemontanine-Related Alkaloids via Tandem Reformatsky Aza-Claisen Rearrangement
- Suh, Young-Ger;
- Lim, Changjin;
- Sim, Jaehoon;
- Lee, Jae Kyun;
- Surh, Young-Joon;
- ... Paek, Seung-Mann
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10초록
A divergent synthetic methodology for a tabernaemontanine-related alkaloid was developed. The synthetic route features practical improvements in the Pictet-Spengler cyclization for the tetrahydro-fi-carboline intermediate and an unprecedented tandem Reformatsky aza-Claisen rearrangement to create the core carbon skeleton and stereochemistries of tabernaemontanine-related alkaloids.
키워드
ENANTIOSPECIFIC TOTAL-SYNTHESIS; INDOLE ALKALOIDS; BISINDOLE ALKALOIDS; TABEMAEMONTANA; VOBASINE
- 제목
- Construction of the Azacyclic Core of Tabernaemontanine-Related Alkaloids via Tandem Reformatsky Aza-Claisen Rearrangement
- 저자
- Suh, Young-Ger; Lim, Changjin; Sim, Jaehoon; Lee, Jae Kyun; Surh, Young-Joon; Paek, Seung-Mann
- 발행일
- 2017-02-03
- 유형
- Article
- 권
- 82
- 호
- 3
- 페이지
- 1464 ~ 1470
- 언어
- ENG
- 출판사
- AMER CHEMICAL SOC
- 발행국가
- 미국
- 분량
- 7 페이지
- ISSN
- E 1520-6904
P 0022-3263