A high rate and long-cycle-life anode based on micrometer-sized Pb powder for sodium-ion batteries
Citations

WEB OF SCIENCE

29
Citations

SCOPUS

28

초록

Pb powder was investigated as an active material as anode for sodium-ion batteries. Precisely, a Pb anode comprising micrometer-sized Pb powder modified with multi-walled carbon nanotubes was fabricated. The anode showed an excellent rate capability, as well as reversible capacities of 370 mAh g-1 at 12.8 C (6208 mA g-1). In addition, the Pb anode exhibited a stable cycle life during 1000 cycles at 10 C with a high reversible capacity of 423 mAh g-1. Using electrochemical tests, scanning electron microscopy, and energydispersive X-ray spectroscopy, we revealed the origin of this excellent performance: the micrometer-sized Pb powder undergoes self-healing during cycling, resulting in fiber-like nanometer-sized Pb particles that reinforce the anode structure and provide fast electron transport pathways. (c) 2021 Elsevier B.V. All rights reserved.

키워드

Long cycle lifeSodium-ion batteriesHigh ratePb anodeMicrostructureScanning electron microscopyDOPED CARBON NANOFIBERSHIGH-PERFORMANCE ANODETIN NANOPARTICLESHIGH-CAPACITYELECTRODECATHODENANOSPHERESCHALLENGESULTRAFASTGERMANIUM
제목
A high rate and long-cycle-life anode based on micrometer-sized Pb powder for sodium-ion batteries
저자
Kim, ChanghyeonKim, HuihunSadan, Milan K.Jeon, MinyeongCho, Gyu-BongNam, Tae-HyunCho, Kwon-KooAhn, Jou-HyeonAhn, Hyo-Jun
DOI
10.1016/j.jallcom.2021.161240
발행일
2021-12-15
유형
Article
저널명
Journal of Alloys and Compounds
886