A Calix[4]pyrrole Bearing a Quaternary Ammonium Group: A Fluoride-Selective Anion Receptor

Citations

WEB OF SCIENCE

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초록

A calix[4]pyrrole (1) bearing a quaternary ammonium pendant via its meso phenoxy linker has been synthesized as the bromide salt form. It was revealed by H-1 NMR spectroscopic analyses performed in DMSO-d(6) that receptor 1 binds F- with high affinity and selectivity over other halide anions. The binding of receptor 1 center dot Br- with F- and Cl- takes place by anion metathesis with the anions including F- and Cl-.

키워드

Anion receptorFluorideSelectivityAnion metathesisCalix[4]pyrroleCHEMOSENSORSRECOGNITION
제목
A Calix[4]pyrrole Bearing a Quaternary Ammonium Group: A Fluoride-Selective Anion Receptor
저자
Oh, Ju HyunLee, Joon HwaKim, Sung Kuk
DOI
10.6564/JKMRS.2021.25.4.045
발행일
2021
유형
Article
저널명
Journal of the Korean Magnetic Resonance Society
25
4
페이지
45 ~ 50