Metallosupramolecules of pillar[5]-bis-trithiacrown including a mercury(II) iodide ion-triplet complex

  • Shin, Mingyeong
  • Seo, Sujin
  • Park, In-Hyeok
  • Lee, Eunji
  • Habata, Yoichi
  • ... Lee, Shim Sung
Citations

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초록

A combination of pillar[5]-bis-trithiacrown (L) and mercury(II) halides afforded a monomer complex (Cl--form), a 1-D coordination polymer (Br--form) and a supramolecular ion-triplet complex [(I center dot Hg center dot I)@L] (I--form). In the ion-triplet complex, the host encapsulates the (I--Hg2+-I-) entity via Hg2+center dot center dot center dot pi and C-H center dot center dot center dot I- interactions, reflecting geometrical complementarity.

키워드

CATION-PI INTERACTIONSMETAL CATIONBINDINGGUESTHOSTCOORDINATIONRECOGNITIONHGI2
제목
Metallosupramolecules of pillar[5]-bis-trithiacrown including a mercury(II) iodide ion-triplet complex
저자
Shin, MingyeongSeo, SujinPark, In-HyeokLee, EunjiHabata, YoichiLee, Shim Sung
DOI
10.1039/d0cc03902k
발행일
2020-09
유형
Article
저널명
Chemical Communications
56
70
페이지
10135 ~ 10138