Small asymmetric anthracene-thiophene compounds as organic thin-film transistors
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초록

Anthracene and thiophene compounds are promising materials for OTFTs. We report here, the synthesis, as well as the physical, thermal, and optoelectronic properties of alkyl-substituted asymmetric anthracene-thiophene compounds connected by a bridged triple bond. The target molecules were synthesized using 2-bromoanthracene as the starting material, and the proceeding reactions included alkylation, bromination, and the Sonogashira coupling reaction. The synthesized compounds were both thermally and electrochemically stable. Among the synthesized compounds, HTEA (7a) and DTEA (7b) showed mobility and on/off ratio values of 1.3x10(-1) cm(2)/V s, 2.6 x 10(6) and 2.0x10(-2) cm(2)/V s, 1.0x10(6), respectively. (C) 2013 Elsevier Ltd. All rights reserved.

키워드

Organic thin-film transistorsSonogashira couplingAsymmetric anthracene derivativesSolution processingP-type charge carrier mobilityHIGH-MOBILITYSEMICONDUCTORSPERFORMANCEFLUORENEDERIVATIVESCOPOLYMERS
제목
Small asymmetric anthracene-thiophene compounds as organic thin-film transistors
저자
Shaik, BajiPark, Ji HeeAn, Tae KyuNoh, Young RiYoon, Soon ByungPark, Chan EonYoon, Young JinKim, Yun-HiLee, Sang-Gyeong
DOI
10.1016/j.tet.2013.07.041
발행일
2013-09
유형
Article
저널명
Tetrahedron
69
38
페이지
8191 ~ 8198