ScholarWorks@경상국립대학교

초록

This study explores the production of poly alpha olefin (PAO) from biomass as an environmentally friendly alternative to fossil fuel-based methods, aiming to reduce greenhouse gas (GHG) emissions. The primary goal is to design a process for converting 2,000 metric tons of biomass into PAO daily, integrating biological and chemical pathways. Environmental impact is assessed through a life cycle assessment (LCA), comparing this biomass-based method with traditional fossil fuel-derived processes. Key findings include the successful production of 458 metric tons of PAO, with the LCA revealing a 34.8% reduction in GHG emissions (9.88 kg CO2eq./kg of PAO) compared to fossil fuel-based PAO. Sensitivity analyses on the oligomerization yield (60-70%, base case at 65%) and the recycle ratio of glucose in the bioprocess for octanoic acid production show significant environmental benefits when exceeding a 55% recycle ratio. Additionally, an energy scenario analysis predicts the impact of shifting to renewable energy by 2030. In a scenario where all electric utilities are renewable (RE100 scenario), GHG emissions are estimated at 13.07 kg CO2-eq./kg of PAO, further emphasizing the environmental advantage of biomass-based PAO. This study, through its integration of biological and chemical processes and comprehensive LCA, provides critical insights into the potential of biomass-based materials for reducing GHG emissions, making a substantial contribution to future research in high-value material production from renewable resources.

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