A Microwave Synthesis of Mesoporous NiCo2O4 Nanosheets as Electrode Materials for Lithium-Ion Batteries and Supercapacitors

초록

A facile microwave method was employed to synthesize NiCo2O4 nanosheets as electrode materials for lithium-ion batteries and supercapacitors. The structure and morphology of the materials were characterized by X-ray diffraction, field-emission scanning electron microscopy, transmission electron microscopy and Brunauer-Emmett-Teller methods. Owing to the porous nanosheet structure, the NiCo2O4 electrodes exhibited a high reversible capacity of 891 mAhg(-1) at a current density of 100 mAg(-1), good rate capability and stable cycling performance. When used as electrode materials for supercapacitors, NiCo2O4 nanosheets demonstrated a specific capacitance of 400 Fg(-1) at a current density of 20 Ag-1 and superior cycling stability over 5000 cycles. The excellent electrochemical performance could be ascribed to the thin porous structure of the nanosheets, which provides a high specific surface area to increase the electrode-electrolyte contact area and facilitate rapid ion transport.

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