Iron Disulfide Cathode Material Incorporated in Highly Ordered Mesoporous Carbon for Rechargeable Lithium Ion Batteries

초록

A highly ordered mesoporous carbon@iron disulfide (CMK-5@FeS2) composite was prepared via an in-situ impregnation and sulfurization method. The CMK-5 matrix with excellent conductivity and high surface area not only formed a continuous conductive network to improve the performance of the CMK-5@FeS2 composite, but also provided sufficient space to buffer the volume changes during cycling. The CMK-5@FeS2 cell exhibited excellent electrochemical performance. After 80 cycles, the CMK-5@FeS2 cell showed the discharge capacities of 650 and 380 mAh g(-1) at 2 C and 5 C, respectively. The excellent results show that CMK-5 with unique mesoporous structure can contribute to accelerating ion transfer in the electrode due to the easy accessibility of the electrolyte, which implies CMK-5@FeS2 composite could be a promising cathode active material for rechargeable lithium ion (Li-ion) batteries.

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