Development of novel inorganic yellowish-tacao color pigments, RbBi<sub>1-<i>x</i></sub>Ce<sub><i>x</i></sub>(MoO<sub>4</sub>)<sub>2</s ub> (0 ≤ <i>x</i> ≤ 0.30): revealing crystal structure and color properties
  • Kang, Tae Wook
  • Jeong, Gyu Jin
  • Kim, Jin Ho
  • Bae, Byungseo
  • Kim, Sun Woog
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초록

Inorganic yellowish-tacao color RbBi1-xCex(MoO4)(2) (0 <= x <= 0.30) pigments were synthesized by a conventional solid-state reaction method, followed by characterization of their crystal structure and optical and color properties. RbBi1-xCex(MoO4)(2) (0 <= x <= 0.30) pigments prepared in this study exhibited a single phase of monoclinic system with a space group P2(1)/c (14). They had fine angular grains with an average particle size of 10-15 mu m. The synthesized pigments showed strong optical absorption in the UV and blue light regions due to the ligand-metal charge transfer (LMCT) transition in the host lattice and the 4f -> 5d transition of Ce3+ ion, leading to a yellowish-tacao color. Among the obtained RbBi1-xCex(MoO4)(2) (0 <= x <= 0.30) pigments, the RbBi0.90Ce0.10(MoO4)(2) pigment showed the strongest yellowish-tacao color hue, where the L*, a*, and b* values were 78.3, 14.7, and 38.9, respectively. These pigments showed excellent resistance to UV irradiation.

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제목
Development of novel inorganic yellowish-tacao color pigments, RbBi<sub>1-<i>x</i></sub>Ce<sub><i>x</i></sub>(MoO<sub>4</sub>)<sub>2</s ub> (0 ≤ <i>x</i> ≤ 0.30): revealing crystal structure and color properties
저자
Kang, Tae WookJeong, Gyu JinKim, Jin HoBae, ByungseoKim, Sun Woog
DOI
10.1039/d2nj01134d
발행일
2022-06
유형
Article
저널명
New Journal of Chemistry
46
22
페이지
10722 ~ 10727