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A Thiacalix Basket and Its Anion-Dependent 2-D and 3-DSilver(I) Coordination Polymers via Exo-Coordination
- Ju, Huiyeong;
- Park, In-Hyeok;
- Lee, Eunji;
- Kim, Chungsik;
- Kim, Seulgi;
- ... Lee, Shim Sung;
- 외 2명
WEB OF SCIENCE
6SCOPUS
7초록
Thiacalix[4]arene-bis-1,2;3,4-crown-2 (basket or L) was isolated. Herein we report the first examples of the calix basket complexes. The combination of the basket and silver(I) salts afforded anion-dependent coordination polymers with different dimensionalities. The AgClO4 complex 1, {[Ag-2(L)(CH3OH)(ClO4)(2)]center dot 4CHCl(3)}(n) has a 2-D square-grid network, in which silver(I) atoms link the baskets to form a 1-D ribbon and these are crosslinked by perchlorate ions. While, the AgPF6 complex 2, {[Ag(L)(CH3OH)](PF6)}(n) exhibits a multichannel type 3-D framework with nbo-a topology. Since the basket acts as an ideal exo-coordinating S-4-platform, the topologies of both products are highly sensitive to the anion coordination.
키워드
- 제목
- A Thiacalix Basket and Its Anion-Dependent 2-D and 3-DSilver(I) Coordination Polymers via Exo-Coordination
- 제목 (타언어)
- A Thiacalix <i>Basket</i> and Its Anion-Dependent 2-D and 3-D Silver(I) Coordination Polymers via Exo-Coordination
- 저자
- Ju, Huiyeong; Park, In-Hyeok; Lee, Eunji; Kim, Chungsik; Kim, Seulgi; Kuwahara, Shunsuke; Habata, Yoichi; Lee, Shim Sung
- 발행일
- 2020-01
- 유형
- Article
- 권
- 2020
- 호
- 4
- 페이지
- 356 ~ 360