Discharge properties of all-solid sodium-sulfur battery using poly (ethylene oxide) electrolyte

  • Park, Cheol-Wan; 
  • Ryu, Ho-Suk; 
  • Kim, Ki-Won; 
  • Ahn, Jou-Hyeon; 
  • Lee, Jai-Young; 
  • ... Ahn, Hyo-Jun
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초록

An all-solid sodium/sulfur battery using poly (ethylene oxide) (PEO) polymer electrolyte are prepared and tested at 90 degrees C. Each battery is composed of a solid sulfur electrode, a sodium metal electrode, and a solid PEO polymer electrolyte. During the first discharge, the battery shows plateau potentials at 2.27 and at 1.76 V. The first discharge capacity is 505 mAh g(-1) sulfur at 90 degrees C. The capacity drastically decreases by repeated on charge-discharge cycling but remains at 166 mAh g(-1) sulfur after 10 cycles. The latter value is higher than that reported for a Na/poly (vinylidene difluoride)/S battery at room temperature. (c) 2006 Elsevier B.V. All rights reserved.

키워드

sodium battery; sulfur electrode; poly (ethylene oxide) polymer electrolyte; solid-state battery; capacity; charge-discharge cycling; ELECTROCHEMICAL PROPERTIES; ROOM-TEMPERATURE; ION BATTERIES; CELLS; PERFORMANCE; SYSTEM
제목
Discharge properties of all-solid sodium-sulfur battery using poly (ethylene oxide) electrolyte
저자
Park, Cheol-Wan; Ryu, Ho-Suk; Kim, Ki-Won; Ahn, Jou-Hyeon; Lee, Jai-Young; Ahn, Hyo-Jun
DOI
10.1016/j.jpowsour.2006.11.083
발행일
2007-02-25
유형
Article
저널명
Journal of Power Sources
권
165
호
1
페이지
450 ~ 454