TEGDME 액체 전해질을 사용한 Li/MoS₂ 전지의 충·방전 특성

The Charge-Discharge Performance of Li/MoS₂ Battery with liquid Electrolyte of Tetra(ethylene glycol) Dimethyl Ether(TEGDME)
  • 권정희; 
  • 유호석; 
  • 김기원; 
  • 안주현; 
  • 정용수; 
  • ... 안효준; 
  • 외 1명

초록

We investigated the electrochemical properties of lithium/molybdenum sulfide(Li/MoS₂) using tetra (ethylene glycol) dimethyl ether(TEGDME) electrolyte. The Li/TEGDME/MoS₂ cell showed the first discharge capacity of 288mAhg-1. From the XRD, SEM results of the MoS₂ electrode in various cut-off voltage during charge-discharge process, MoS2 partly changed into Li₂S and Mo during discharge and Li₂S partly recovered into MoS₂ and Li during charge. Full charged MoS₂ electrode showed lump shape of big size, which might be related to agglomerate of MoS₂ particles. Therefore, the degradation might be related to decrease of active material for electrochemical reaction by agglomeration of MoS₂.

키워드

Li/MoS₂ battery; MoS₂ electrode; TEGDME; Charge-discharge process; Li/MoS₂ 전지; MoS₂ 전극; TEGDME 전해질; 충방전 특성
제목
TEGDME 액체 전해질을 사용한 Li/MoS₂ 전지의 충·방전 특성
제목 (타언어)
The Charge-Discharge Performance of Li/MoS₂ Battery with liquid Electrolyte of Tetra(ethylene glycol) Dimethyl Ether(TEGDME)
저자
권정희; 유호석; 김기원; 안주현; 정용수; 이건환; 안효준
발행일
2009
저널명
한국수소및신에너지학회논문집
권
20
호
3
페이지
238 ~ 244