Synthesis and characterization of perfluorinated phenyl-substituted Ir(III) complex for pure green emission

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초록

A new deep green-emitting material, a 3,5-bis(trifluoromethyl) phenylene-substituted iridium(III) complex, fac-tris[2-(30',5'-bis(trifluoromethyl) biphenyl-3-yl) pyridine] iridium (Ir(mtfppy)(3)), was synthesized. Introducing bulky 3,5-bis(trifluoromethyl)phenylene to the metaposition of pyridyl-phenyl results in blue-shifted narrow emission compared to that of Ir(ppy)(3). The organic light-emitting diode (OLED) based on Ir(mtfppy)(3) shows a maximum external quantum efficiency (EQE) of 23.2% with the CIE coordinates of (0.26, 0.63) without strong microcavity effect.

키워드

LIGHT-EMITTING-DIODES; CYCLOMETALATED IRIDIUM COMPLEXES; DEEP-BLUE PHOSPHORESCENCE; ELECTROPHOSPHORESCENT DEVICES; EFFICIENT; PERFORMANCE; EMITTERS; LIGANDS; OLEDS; RED
제목
Synthesis and characterization of perfluorinated phenyl-substituted Ir(III) complex for pure green emission
저자
Kim, Myeong-Jong; Yoo, Seung-Jun; Hwang, Jaeyoung; Park, Sung-Jin; Kang, Jae-Wook; Kim, Yun-Hi; Kim, Jang-Joo; Kwon, Soon-Ki
DOI
10.1039/c6tc05558c
발행일
2017-03
유형
Article
저널명
Journal of Materials Chemistry C
권
5
호
12
페이지
3107 ~ 3111