Ligand- and anion-directed assembly of exo-coordinated Mercury(II) halide complexes with O2S2-Donor macrocycles

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초록

Assembly reactions of mercury(II) halides (Cl, Br, and 1) with two 02S2 macrocycles (L-1 and L-2) having different interclonor (S center dot center dot center dot S) distances were investigated, and four types of supramolecular complexes (1-4b) were obtained depending on the S center dot center dot center dot S distances as well as the size of the halide anions. Photoluminescence of these compounds was also studied.

키워드

SUPRAMOLECULAR SILVER(I) COMPLEXES; PALLADIUM(II) COMPLEXES; CRYSTAL-STRUCTURES; CROWN-ETHERS; CHEMISTRY; ISOMERISM; PEPTIDES; POLYMERS; NETWORK; EXAMPLE
제목
Ligand- and anion-directed assembly of exo-coordinated Mercury(II) halide complexes with O2S2-Donor macrocycles
저자
Lee, So Young; Park, Sunhong; Kim, Hyun Jee; Jung, Jong Hwa; Lee, Shim Sung
DOI
10.1021/ic702496e
발행일
2008-03-17
유형
Article
저널명
Inorganic Chemistry
권
47
호
6
페이지
1913 ~ 1915