상세 보기
H-D exchange of pyrrolic NH protons prompted by fluoride in aprotic DMSO-d6
H-D exchange of pyrrolic NH protons prompted by fluoride in aprotic DMSO-d6
Citations
WEB OF SCIENCE
0Citations
SCOPUS
0초록
The binding feature of bipyrrole-strapped calix[4]pyrrole 1 for the fluoride anion was examined by a combination of 1H and 19F NMR spectroscopy in DMSO-d6 . Receptor 1 was found to bind the fluoride anion with high affinity via two step-process. Fluoride binding to receptor 1 was proved to facilitate deuterium exchange of the pyrrolic protons in the nominally aprotic deuterated solvent of DMSO-d6.
키워드
Fluoride; deuterium exchange; anion receptor; calix[4]pyrrole; aprotic solvent; WATER FLUORIDATION; ANION; RECOGNITION; HIGHLIGHTS
- 제목
- H-D exchange of pyrrolic NH protons prompted by fluoride in aprotic DMSO-d6
- 제목 (타언어)
- H-D exchange of pyrrolic NH protons prompted by fluoride in aprotic DMSO-d6
- 저자
- 김성국
- 발행일
- 2024-12
- 유형
- Article
- 권
- 28
- 호
- 4
- 페이지
- 38 ~ 43