Small triiminopyrrolic molecular cage with high affinity and selectivity for fluoride

  • Han, Hye Jin; 
  • Oh, Ju Hyun; 
  • Sessler, Jonathan L.; 
  • Kim, Sung Kuk
Citations

WEB OF SCIENCE

37
Citations

SCOPUS

35

초록

A small molecular cage (4) with high affinity and complete selectivity for fluoride to the limit of detection over other competing small anions was synthesized. Cage 4 was also found to retain the encapsulated fluoride anion within its cavity even after one or two pyrrolic NH protons were subject to deprotonation.

키워드

RECEPTOR CHEMISTRY HIGHLIGHTS; WATER FLUORIDATION; UNITED-STATES; ANION; RECOGNITION; CHEMOSENSORS; HEALTH
제목
Small triiminopyrrolic molecular cage with high affinity and selectivity for fluoride
저자
Han, Hye Jin; Oh, Ju Hyun; Sessler, Jonathan L.; Kim, Sung Kuk
DOI
10.1039/c9cc05613k
발행일
2019-09-18
유형
Article
저널명
Chemical Communications
권
55
호
73
페이지
10876 ~ 10879