Electrochemical properties of lithium/sulfur-polyacrylonitrile-carbon nanotube composite cells using ether-based electrolyte at high rate
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초록

A sulfur-polyacrylonitrile-carbon nanotube (SPANC) composite is prepared by mixing and heat treatment of sulfur, polyacrylonitrile, and carbon nanotubes, with a high sulfur content of 61.94 wt%. The electrochemical properties of a Li/SPANC cell are investigated using 1,2-dimethoxyethan (ethylene glycol dimethyl ether, DME) and 1,3-dioxlane (ethylene glycol methylene ether, DOL) electrolytes. The Li/SPANC cell using the ether-based electrolytes shows high first discharge capacity of 1,037 mAh g(-1) at a rate of 0.1 C. And at a high rate of 1 C, it presents excellent cyclability, yielding a first discharge capacity of 500 mAh g(-1) and retaining 80% of this capacity at the 100th cycle.

키워드

CompositesElectrochemical propertiesEnergy storageCATHODE MATERIALSCYCLE LIFESULFURPERFORMANCEBATTERYPRECURSORGRAPHENEBINDER
제목
Electrochemical properties of lithium/sulfur-polyacrylonitrile-carbon nanotube composite cells using ether-based electrolyte at high rate
저자
Kim, ChanghyeonWang, QingReddy, N. SubbaKim, HuihoonCho, Gyu-BongAhn, Jou-HyeonKim, Ki-WonRyu, Ho-sukKim, YoungchulYeon, Sun-hwaAhn, Hyo-Jun
DOI
10.36410/jcpr.2015.16.2.199
발행일
2015-04
유형
Article
저널명
Journal of Ceramic Processing Research
16
2
페이지
199 ~ 202