상세 보기
- Jung, Taejung;
- Jin, Youngho;
- Moon, Joon Ha;
- Seong, Honggyu;
- Kim, Geongil;
- ... Kwon, Seung-Ryong;
- ... Kuk Kim, Sung;
- ... Choi, Jaewon;
- 외 2명
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0초록
Antimony selenide (Sb2Se3) is a promising electrode material for sodium-ion batteries (SIBs) due to its high theoretical capacity. However, volume expansion during sodiation/desodiation and the low conductivity of Sb2Se3 reduce the electrochemical performance. Herein, we synthesized Sb2Se3 nanorods (NRs) and combined them with multi-walled carbon nanotubes (MWCNTs) using one-step composite process to address these issues. MWCNTs can accommodate volume expansion and provide high conductivity. The fabricated Sb2Se3 NRs@MWCNT electrode exhibits improved cycle performance and cyclic stability without additional conductive carbons. The Sb2Se3 NRs@MWCNT electrode showed an enhanced specific capacity of 440 mAhg−1 at a current density of 0.1 Ag−1, compared to 220 mAhg−1 for the Sb2Se3 NRs electrode. Additionally, it exhibited good stability at high current density. The in-situ electrochemical impedance spectroscopy (EIS) and Galvanostatic intermittent titration technique (GITT) were used to estimate the electrochemical properties and kinetics of Sb2Se3 NRs@MWCNT. These results showed that Sb2Se3 NRs@MWCNT have the potential as a conductive-free anode material in SIBs. © 2024 Wiley-VCH GmbH.
키워드
- 제목
- Synthesis of Rod-Like Sb2Se3@MWCNT as Conductive-Additive Free Anode for Sodium-Ion Batteries
- 저자
- Jung, Taejung; Jin, Youngho; Moon, Joon Ha; Seong, Honggyu; Kim, Geongil; Yoo, Hyerin; Lee, Seunghui; Kwon, Seung-Ryong; Kuk Kim, Sung; Choi, Jaewon
- 발행일
- 2025-02
- 유형
- Article; Early Access
- 저널명
- Batteries & Supercaps
- 권
- 8
- 호
- 2