Highly sulfonated polymer-grafted graphene oxide composite membranes for proton exchange membrane fuel cells

  • Lee, Hyunhee; 
  • Han, Jusung; 
  • Kim, Kihyun; 
  • Kim, Junghwan; 
  • Kim, Eunki; 
  • 외 2명
Citations

WEB OF SCIENCE

64
Citations

SCOPUS

77

초록

Sulfonated poly(arylene ether sulfone) (SPAES) composite membranes were prepared using graphene oxide (GO) and sulfonated poly(arylene thioether sulfone)-grafted graphene oxide (SATS-GO) as fillers for proton exchange membrane fuel cell (PEMFC) applications. When GO and SATS-GO were mixed with SPAES to form the composite membranes, dimensional stability, chemical stability, and mechanical strength were improved. The composite membranes containing SATS-GO especially showed higher proton conductivity than the pristine SPAES and the composite membrane containing GO because of highly sulfonated polymer (SATS) introduced on GO surface. Furthermore, the sulfonic acid groups in SATS-GO can increase the compatibility between the filler and matrix polymer. (C) 2019 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

키워드

Sulfonated poly(arylene ether sulfone); Graphene oxide; Composite membranes; Proton exchange membrane; Fuel cell; POLY(ARYLENE ETHER SULFONE); ELECTROLYTE MEMBRANES; MECHANICAL-PROPERTIES; SIDE-CHAINS; KETONE); COPOLYMERS; CONDUCTIVITY; PERFORMANCE; ENHANCEMENT; DURABILITY
제목
Highly sulfonated polymer-grafted graphene oxide composite membranes for proton exchange membrane fuel cells
저자
Lee, Hyunhee; Han, Jusung; Kim, Kihyun; Kim, Junghwan; Kim, Eunki; Shin, Huiseob; Lee, Jong-Chan
DOI
10.1016/j.jiec.2019.03.012
발행일
2019-06
유형
Article
저널명
Journal of Industrial and Engineering Chemistry
권
74
페이지
223 ~ 232