Solution Processable Symmetric 4-Alkylethynylbenzene End-Capped Anthracene Derivatives
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초록

New candidates composed of anthracene and 4-alkylethynylbenzene end-capped oligomers for OTFTs were synthesized under Sonogashira coupling reaction conditions. All oligomers were characterized by FT-IR, mass, UV-visible, and PL emission spectrum analyses, cyclic voltammetry (CV), differential scanning calorimetry (DSC), thermal gravimetric analysis (TGA), H-1-NMR, and C-13-NMR. Investigation of their physical properties showed that the oligomers had high oxidation potential and thermal stability. Thin films of DHPEAnt and DDPEAnt were characterized by spin coating them onto Si/SiO2 to fabricate top-contact OTFTs. The devices prepared using DHPEAnt and DDPEAnt showed hole field-effect mobilities of 4.0 x 10(-3) cm(2)/Vs and 2.0 x 10(-3) cm(2)/Vs, respectively, for solution-processed OTFTs.

키워드

Solution-processingAnthracene derivativesSonogashira couplingOrganic thin-film transistorsHIGH-PERFORMANCE SEMICONDUCTORSORGANIC SEMICONDUCTORSOLIGOMERSTRANSISTORS
제목
Solution Processable Symmetric 4-Alkylethynylbenzene End-Capped Anthracene Derivatives
저자
Jang, Sang HunKim, HyunjinHwang, Min JiJeong, Eun BinYun, Hui JunLee, Dong HoonKim, Yun-HiPark, Chan EonYoon, Yong-JinKwon, Soon-KiLee, Sang-Gyeong
DOI
10.5012/bkcs.2012.33.2.541
발행일
2012-02
유형
Article
저널명
Bulletin of the Korean Chemical Society
33
2
페이지
541 ~ 548