Electrochemical properties of new organic radical materials for lithium secondary batteries

초록

The use of ionic liquid (IL)-supported organic radicals as cathode-active materials in lithium secondary batteries is reported in this article. Two different types of IL-supported organic radicals based on the 2,2,6.6-tetramethyl-1-piperidinyloxy (TEMPO) radical and imidazolium hexafluorophosphate IL were synthesized. The first type is a mono-radical with one unit of TEMPO and the second is a symmetrical di-radical with 2 U of TEMPO; both are viscous liquids at 25 degrees C. The radicals exhibit electrochemical activity at similar to 3.5V versus Li/Li+ as revealed in the cyclic voltammetry tests. The organic radical batteries (ORBs) with these materials as the cathode, a lithium metal anode and 1 M LiPF6 in EC/DMC electrolyte exhibited good performance at room temperature during the charge-discharge and cycling tests. The batteries exhibited specific capacities of 59 and 80 mAh g(-1) at 1 C-rate with the mono- and di-radicals as the cathodes, respectively, resulting in 100% utilization of the materials. The performance degradation with increasing C-rate is very minimal for the ORBs, thus demonstrating good rate capability. (C) 2008 Elsevier B.V. All rights reserved.

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