Analysis of curing behavior of endo-dicyclopentadiene using different amounts of decelerator solution

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초록

The curing kinetics of endo-dicyclopentadiene (endo-DCPD) was analyzed using isothermal differential scanning calorimetry by experimentally acquiring kinetic parameters according to model fitting approaches. To investigate the effect of the decelerator, the curing kinetics of endo-DCPD with different amounts of decelerator solutions was also examined. The result of the developed model was in good agreement with the experimental data. The results showed that the decelerator had an effect on the delay of a reaction process and slowed down the curing process. The impact properties of glass fiber reinforced polydicyclopentadiene (p-DCPD) with different amounts of decelerator solutions were evaluated and compared with that of the glass fiber reinforced p-DCPD to investigate the effect of the decelerators. The impact energy was shown to decrease with increasing wt. % of decelerators from 0.5 wt % to 2.0 wt % with values from 10.75 to 15.89%, respectively.

키워드

Endo-dicyclopentadiene (endo-DCPD); Curing kinetics; Decelerators; Glass fiber reinforced polydicyclopentadiene (p-DCPD); OPENING METATHESIS POLYMERIZATION; CURE KINETICS; EPOXY CURE; COMPOSITES; CATALYSTS; RESINS; MODEL
제목
Analysis of curing behavior of endo-dicyclopentadiene using different amounts of decelerator solution
저자
Yoo, Hyeong Min; Jeon, Ji Ho; Li, Mei-Xian; Lee, Woo Il; Choi, Sung Woong
DOI
10.1016/j.compositesb.2018.12.068
발행일
2019-03
유형
Article
저널명
Composites Part B: Engineering
권
161
페이지
439 ~ 454