Enhanced electrical properties of Li-salts doped mesoporous TiO2 in perovskite solar cells
  • Kim, Minjin
  • Choi, In-woo
  • Choi, Seung Ju
  • Song, Ji Won
  • Mo, Sung-In
  • ... Kim, Gi-Hwan
  • 외 5명
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초록

The charge transferability of the electron transfer layers (ETLs) is important for achieving high performance in mesoscopic (mp) perovskite solar cells (PSCs). However, because of the low electron extraction efficiency of TiO2, lithium doping is essentially required. In this work, we compared the electrical properties of mp-TiO2 doped with Li-salts with different anions-LiTFSI, Li2CO3, LiCl, and LiF. Interestingly, we found that the anions of the Li-salt dopants affect the electrical properties of the ETLs and the solar cell performance. The Li2CO3 doping of mp-TiO2 led to conduction bands deeper than those of pristine mp-TiO2 or other doped mp-TiO2. The maximum efficiency of 25.28% and certified efficiency of 24.68% (Newport) was obtained by using Li2CO3 dopant. This optimization of the ETLs properties is expected to greatly contribute to the progress of PSCs by leading to further increases in their efficiency.

키워드

25% efficiencycharge transportconduction bandelectron transfer layermesoporous TiO2 doping with Li2CO3perovskite solar cellHIGHLY EFFICIENTTRANSPORT LAYERSTABILITY ENHANCEMENTHYSTERESIS-FREEGRAPHENE OXIDEPERFORMANCEDIFFUSIONLENGTHSNANORODSSTATE
제목
Enhanced electrical properties of Li-salts doped mesoporous TiO2 in perovskite solar cells
저자
Kim, MinjinChoi, In-wooChoi, Seung JuSong, Ji WonMo, Sung-InAn, Jeong-HoJo, YimhyunAhn, SeJinAhn, Seoung KyuKim, Gi-HwanKim, Dong Suk
DOI
10.1016/j.joule.2021.02.007
발행일
2021-03
유형
Article
저널명
Joule
5
3
페이지
659 ~ 672