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초록
2,2'-Bithiophene and halogenated-2,2'-bithiophenes were halogenated with 2-halo-4.5-dichloropyridazin-3(2H)-one in the presence of zinc halide to give selectively the corresponding dihalo-, trihalo-, and tetrahalo-2,2'-bithiophenes involving the same or different halogens in excellent yields, respectively.
키워드
bithiophene; halogenation; chlorination; bromination; 2-halopyridazin-3(2H)-one; CATALYZED COUPLING REACTIONS; ORGANIC ELECTRONICS; FACILE SYNTHESIS; THIOPHENE; DERIVATIVES; OLIGOMERS; EFFICIENT; OLIGOTHIOPHENES; ESTERIFICATION; SYSTEM
- 제목
- Selective Halogenation of Bithiophenes Using 2-Halopyridazin-3(2H)-ones under Ambient Conditions
- 저자
- Jung, Kwang-Ju; Kang, Seung Beom; Won, Ju-Eun; Park, Song-Eun; Park, Ki Hun; Park, Jong Keun; Lee, Sang-Gyeong; Yoon, Yong-Jin
- 발행일
- 2009-02-13
- 유형
- Article
- 저널명
- Synlett
- 호
- 3
- 페이지
- 490 ~ 494