ScholarWorks@경상국립대학교

초록

The advancement of high-performance sodium-ion batteries (SIBs) necessitates cathode materials that exhibit both structural robustness and long-term electrochemical stability. Na3V2(PO4)3 (NVP), with its NASICON-type framework, is a promising candidate; however, its inherently low electronic conductivity restricts full capacity utilization. In this study, carbon-coated and Cu-substituted Na3V2(PO4)3 (NVCP) composites were synthesized via a solid-state reaction using agarose as a carbon source. Structural and morphological analyses confirmed the successful incorporation of Cu2+ ions into the rhombohedral lattice without disrupting the crystal structure and the formation of uniform conductive carbon layers. The substitution of Cu2+ induced increased carbon disorder and partial oxidation of V3+ to V4+, contributing to enhanced electronic conductivity. Consequently, NVCP exhibited excellent long-term cycling performance, maintaining over 99% of its initial capacity after 500 cycles at 0.5 C. Furthermore, the electrode demonstrated outstanding high-rate capabilities, with a capacity recovery of 97.98% after cycling at 20 C and returning to lower current densities. These findings demonstrate that Cu substitution combined with carbon coating synergistically enhances structural integrity and Na+ transport, offering an effective approach to engineer high-performance cathodes for next-generation SIBs.

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