Electrochemical conversion of biomass-derived aldehydes into fine chemicals and hydrogen: A review
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초록

The decrease in fossil fuel usage and the projected 28% increase in the global energy demand by 2040 are calling for advanced methods to convert modern biomass into fine chemicals. For instance, biomass-derived aldehydes appear as promising substitutes for the chemical and fuel industries. Here, we review electrochemical upgrading of furfural and 5-hydroxymethylfurfural with a focus on catalysis and selectivity mechanisms. We also present hybrid water electrolysis systems for production of hydrogen and chemicals. We discuss electrochemical oxidation or hydrogenation of furfural and 5-hydroxymethylfurfural using metal oxides, noble metals, transition metal nanoparticles and alloys, and nonoxides. We compare electrochemical processes with combustion, chemical, thermochemical, and biochemical processes for biomass conversion.

키워드

Biomass-derived aldehydesFurfural5-HydroxymethylfurfuralElectrochemical oxidizationHydrogenationHybrid water electrolyzerValue-added chemicalsHydrogen fuelPHASE SELECTIVE HYDROGENATIONSINGLE-REACTOR PROCESSFURFURYL ALCOHOLBIO-OILHYDROTHERMAL CARBONIZATIONEFFICIENT CONVERSIONOXIDATIONACIDPDPYROLYSIS
제목
Electrochemical conversion of biomass-derived aldehydes into fine chemicals and hydrogen: A review
저자
Theerthagiri, JayaramanKaruppasamy, K.Park, JuhyeonRahamathulla, NihilaKumari, M. L. ArunaSouza, Marcielli K. R.Cardoso, Eduardo S. F.Murthy, Arun PrasadMaia, GilbertoKim, Hyun-SeokChoi, Myong Yong
DOI
10.1007/s10311-022-01543-5
발행일
2023-06
유형
Review
저널명
Environmental Chemistry Letters
21
3
페이지
1555 ~ 1583