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벤질알코올과 아세토나이트릴의 반응을 통한 -hydroxynitrile의 전기화학적 합성
Electrochemical Synthesis of β-Hydroxynitrile by addition of Acetonitrile into Benzyl Alcohol
- Choi, H.;
- An, J.;
- Kwon, K.-Y.
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1초록
β-Hydroxynitrile and β-ketonitrile were synthesized by the electrochemical oxidation of benzyl alcohol in an acetonitrile solvent. β-Hydroxynitrile was prepared by the reaction between benzaldehyde from the oxidation of benzyl alcohol and acetonitrile anion which was produced from the electrochemical reduction of acetonitrile. β-Hydroxynitrile was finally electrochemically converted into β-ketonitrile by applying 20 mA of current for 3 h. We demonstrated that β-hydroxynitrile or β-ketonitrile syntheses were prepared by electrochemical oxidation of benzyl alcohol with a commonly used Pt electrode at room temperature. ? 2022 The Korean Society of Industrial and Engineering Chemistry. All rights reserved.
키워드
Cyanomethylation; Electrooxidation; Tetrabutylammonium perchlorate; β-hydroxynitrile
- 제목
- 벤질알코올과 아세토나이트릴의 반응을 통한 -hydroxynitrile의 전기화학적 합성
- 제목 (타언어)
- Electrochemical Synthesis of β-Hydroxynitrile by addition of Acetonitrile into Benzyl Alcohol
- 저자
- Choi, H.; An, J.; Kwon, K.-Y.
- 발행일
- 2022-08
- 유형
- Article
- 저널명
- 공업화학
- 권
- 33
- 호
- 4
- 페이지
- 436 ~ 439