ScholarWorks@경상국립대학교

초록

The exciton behavior of a new synthetic material, 11-phenyl-11H-9,16-dioxa-11-aza-4b-boraindeno[1,2-a]naphtho[3,2,1-de]anthracene (Ph-OBNA), which displays a multi-resonance effect, and bis[4-(9,9-dimethyl-9,10-dihydroacridine)phenyl]sulfone (DMAC-DPS) with a donor-acceptor-donor structure was analyzed. First, we conducted quantum mechanical simulations based on long-range theory (LC-omega PBE) to predict k(RISC), and we confirmed the effect of the luminescence behavior by analyzing aggregation-caused quenching (ACQ) according to pi-pi stacking and aggregation-induced emission (AIE) behavior. Actually, thermally activated delayed fluorescence materials showing ACQ and AIE behavior exhibited different triplet-triplet annihilation (TTA) and singlet-triplet annihilation (STA) rate constants. Interestingly, DMAC-DPS exhibited a restricted exciton concentration quenching behavior based on an observed AIE owing to its inhibited molecular stacking behavior. On the other hand, Ph-OBNA demonstrated somewhat reduced TTA and STA behavior due to an ACQ behavior originating from excimer formation at high concentrations. Despite this difference, both materials demonstrated a hyperfluorescence behavior that can be used to achieve moderately high device efficiency compared with that obtained from common fluorescence emitters.

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