Dimethylsilyl-linked anthracene-pyrene dimers and their efficient triplet-triplet annihilation in organic light emitting diodes

초록

New deep blue emitters containing an sp(3)-hybridised tetrahedral silicon core with dimethyl groups, 9,10-biarylanthracene, and pyrene were synthesised. The pyrene group, with planar pi-conjugation and a slightly larger energy gap than that of anthracene, is expected to work as an intramolecular host group in organic light emitting diodes (OLEDs). Density functional theory (DFT-B3LYP) and time-dependent DFT calculations for molecular orbitals and excited states of pyrene and anthracene units showed the possibility of intramolecular energy transfer and a triplet-triplet annihilation (TTA) process. The maximum external quantum efficiencies (EQEs) of non-doped devices using PA1N and PA2N were 4.7% and 4.8%, respectively, while the maximum EQEs of doped devices using PA1N and PA2N as dopants (3 wt%) were 4.5% and 3.6%, respectively. The EQE of the non-doped device with a low photoluminescence quantum yield (PLQY) (14%) was higher than that of the doped device with a high PLQY (74%), which resulted from the existence of a contribution reproducing radiative S-1 excitons from nonradiative T-1 excitons in the non-doped devices. Both non-doped and doped devices using PA1N and PA2N showed high color pure blue emission. [ Commission Internationale de l'Eclairage coordinates, CIE (x,y), of the non-doped device were (0.16,0.08) for PA1N and (0.15,0.10) for PA2N.]

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