A First Synthesis and Physical Properties of Asymmetric Anthracenes-Thiophenes Bridged with Ethylene
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초록

Here we report our recent result of a new semiconductor material, which has an asymmetric structure. The synthesized molecules consist of anthracene and thiophene connected by bridged ethylene and substituted with hexyl or dodecyl groups as pendants. The semiconductors were synthesized using a McMurry coupling reaction between anthracene-2-carbaldehyde and corresponding 5-hexyl(or dodecyl)thiophene-2-carbaldehyde. A first investigation of synthesized asymmetry AVHT (9a) and AVDT (9b) for the physical properties showed that they have high oxidation potential and thermal stability. The devices prepared by using AVHT (9a) and AVDT (9b) showed the mobility of 2.6 x 10(-2) cm(2)/Vs and 4.4 x 10(-3) cm(2)/Vs, respectively, in solution processed OTFTs.

키워드

Organic thin-film transistorsMcMurry couplingAsymmetric anthracene derivativesSolution-processingp-Type charge carrier mobilityFIELD-EFFECT TRANSISTORSTHIN-FILM TRANSISTORSEND-CAPPED OLIGOMERSHIGH-PERFORMANCE SEMICONDUCTORSORGANIC SEMICONDUCTORSDERIVATIVESNAPHTHALENEMOBILITYDESIGN
제목
A First Synthesis and Physical Properties of Asymmetric Anthracenes-Thiophenes Bridged with Ethylene
저자
Hwang, Min JiPark, Ji HeeJeong, Eun BinKang, IlLee, Dong HoonPark, Chan EonSingh, O. M.Choi, HoJuneKim, Yun-HiYoon, Yong JinKwon, Soon-KiLee, Sang-Gyeong
DOI
10.5012/bkcs.2012.33.11.3810
발행일
2012-11
유형
Article
저널명
Bulletin of the Korean Chemical Society
33
11
페이지
3810 ~ 3816